As the CTD didn’t directly record density data, density must be calculated from temperature and salinity data. Because of the impracticality of performing this calculation upon all temperature and salinity records, density has been calculated at highest and lowest temperature and salinity values. From these four values the highest and lowest density was then used in the above calculation. Often the lowest temperature and highest salinity coincided (and vice versa), demonstrating the legitimacy of this ‘back of envelope’ approach.
The phosphate concentrations show an inverse relationship with salinity throughout the tidal cycle (fig. 22). The depth profiles show that phosphate concentrations tend to be higher towards the head of estuary, concentrations up to ≈0.9μmol/l, whilst those towards the mouth concentrations tend to be lower, up to ≈0.5μmol/l. The estuarine mixing diagram displays that phosphate is added to the estuary, most significantly at 25psu with a concentration over 3.0 μmol/l.
The silicon concentrations also show an inverse relationship with salinity over the tidal cycle (fig. 23). The profiles with depth also show that higher concentrations of salinity are reached further up the estuary, up to ≈7.0 μmol/l, whereas the maximum for the bottom half of the estuary is ≈4.4μmol/l. The estuarine mixing diagram shows silicon behaves conservatively up to a psu≈15, after this salinity silicon is removed from the estuary.
The dissolved oxygen sampled in the surface waters at the pontoon (fig. 22) showed the ebb tide to bring oxygenated water, causing a dissolved O2 peak of 103.1% at 11.00GMT indicating super saturation. The flood tide appears to bring two water masses past the station, initially a water mass significantly lower in O2, a minimum 61.9% reached at 14.00GMT. This is followed by a water mass with higher O2 saturation recovering to 89.0% by 17.00GMT.
The phytoplankton counts indicated diatoms to be at least 86% dominant at all the sampling stations and the pontoon. The most common phytoplankton families seen in the estuary were the Chaetocerotaceae (67.49%), Naked dinoflagellates (9.17%), Thalassiosiraceae (8.38%) and Skeletonemaceae (6.03%). By comparing the phytoplankton communities at the head and mouth of the estuary it can be seen there is very little change, the only significant change being an increase in the percentage of Skeletonemaceae towards the head (fig. 26). Numbers/L of both dinoflagellates and diatoms increased greatly at 12:00GMT at the pontoon; this seems to occur just after high tide.
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